Corrosion Inhibition characteristics of Reinforced Steel in H2SO4 by benzoyl Thiourea

نویسندگان

چکیده

In The adsorption and corrosion inhibition performance of 3,3-diethyl(4-Chloro)benzoylthiourea, ClDEBT, at reinforced steel in H2SO4 interface was examined using gravimetric method 303.15 K. effectiveness ClDEBT improved by increasing the concentration. data on surface were fitted to Langmuir, Temkin thermodynamic–kinetic isotherms, some thermo-dynamics functions as α, y, f, ΔGads Kads obtained. Activation energies 35.69 55.99 kJ mol−1 for processes observed presence absence benzoylthiourea inhibitor, respectively. thiourea inhibitor found be spontaneous exothermic. Quantum parameters highest & lowest occupied molecular orbital energy (EHOMO) (ELUMO), gap (ΔE), determined correlated experimental data.

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Corrosion Inhibition of Mild Steel in 1 M H2SO4 by Polyvinyl Pyrrolidone and Synergistic Iodide Additives

The corrosion inhibition of mild steel in 1M H2SO4 by polyvinyl pyrrolidone (PVP) and the synergistic effect of iodide ions were investigated using weight loss and hydrogen evolution methods in the temperature range of 30 – 60 o C. The corrosion rates of mild steel decreased with the increasing concentration of PVP, while the inhibition efficiency (%I) increased. The inhibition efficiency of PV...

متن کامل

Corrosion Inhibition of API 5L Carbon Steel by Nettle Leaves Hydroalcoholic Extract in a 0.5 M H2SO4 Solution

In this work, electrochemical methods such as Tafel polarization and electrochemical impedance spectroscopy (EIS) were used to study the inhibition efficiency of Nettle leaves hydroalcoholic extract as a green corrosion inhibitor of API 5L carbon steel in 0.5 M H2SO4 solution. The results showed that the inhibition efficiency was increased with increasing the concentration of the extract and th...

متن کامل

Inhibition of mild steel corrosion in acid media by N-benzyl-N′-phenyl thiourea

The inhibition effect of N-benzyl-N′-phenyl thiourea (BPTU) on the corrosion of mild steel in 0.01 and 0.05 N HCl medium has been investigated by potentiostatic polarization technique. Results obtained reveal that BPTU is an efficient anodic inhibitor with greater than 94% of efficiency in the range of temperature studied. The adsorption of inhibitor on the mild steel surface obeys the Temkins’...

متن کامل

Inhibition Effect of 2,2’-bipyridyl on the Corrosion of Austenitic Stainless Steel in 0.5M H2SO4

The corrosion inhibition of AISI309 austenitic stainless steel by 2,2'-Bipyridyl in 0.5M H 2 SO 4 at 298K was studied using the mass loss’ method, the potentiodynamic polarization (Tafel), the linear polarization (LRP) and the electrochemical impedance spectroscopy (EIS). The results showed a mixed inhibition mode and an increase in the charge transfer resistance, due to inhibitor molecules’ ad...

متن کامل

Branched Polymers and their Application in Corrosion Inhibition for Mild Steel in 1M H2SO4 Medium

The adsorption and corrosion inhibiting effect of branched polymers (BATP, BAAZ, BETP & BEAZ) on mild steel in 1M H2SO4 at 30±1°C was investigated using gravimetric, electrochemical impedance spectroscopy (EIS), and potentiodynamic polarization techniques. The experimental findings revealed that BATP inhibited the corrosion reaction in the acid environment to greater extend compared to BAAZ, BE...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: ???? ?????? ?????? ??????????

سال: 2021

ISSN: ['2708-8251', '2521-9200']

DOI: https://doi.org/10.51984/jopas.v20i2.1591